儀器：GC-氣相色譜儀，氫焰檢測(cè)器(FID)。

柱：Chromosorb 101 HP60～80目；玻璃柱長(zhǎng)2m，φ 3 mm。柱溫：120℃。

檢測(cè)器：150℃。

氣化器：150℃。

載氣量：氮?dú)猓?5 mL/min。

氫氣：35 mL/min。

空氣：350 mL/min。

柱前壓約為108 kPa。
應(yīng)用：GB 15979-2002 一次性使用衛(wèi)生用品衛(wèi)生標(biāo)準(zhǔn)

浩瀚色譜（山東）應(yīng)用技術(shù)開(kāi)發(fā)有限公司建立了吹掃捕集-氣相色譜/質(zhì)譜法測(cè)定醫(yī)用口罩中痕量環(huán)氧乙烷的方法。采用吹掃捕集法對(duì)醫(yī)用口罩中環(huán)氧乙烷進(jìn)行富集,熱脫附后導(dǎo)入氣相色譜/質(zhì)譜儀,并選用選擇離子模式（SIM）進(jìn)行檢測(cè),內(nèi)標(biāo)法定量。結(jié)果表明:環(huán)氧乙烷在5.0～200μg/L質(zhì)量濃度范圍內(nèi)線性關(guān)系良好,相關(guān)系數(shù)為0.9992,方法檢出限為0.03μg/g,定量限為0.10μg/g。三個(gè)不同濃度加標(biāo)水平（5.0μg/L、20μg/L、80μg/L）的回收率為97.59%～115.95%,相對(duì)標(biāo)準(zhǔn)偏差（RSD,n=6）為3.07%～7.48%。該方法操作簡(jiǎn)單、富集效率高、快速準(zhǔn)確,適用于大批量醫(yī)用口罩樣品測(cè)定。 

測(cè)定醫(yī)用口罩中痕量環(huán)氧乙烷GB 15979-2002   測(cè)試譜圖：



Determination of trace amounts of ethylene oxide in medical masks GB 15979-2002
Determination of trace amounts of ethylene oxide in medical masks GB 15979-2002 Details:

Apparatus: GC- gas chromatograph, hydrogen flame detector (FID).

Column: Chromosorb 101 HP60-80 mesh; glass column length 2m, φ 3 mm. Column temperature: 120°C.

Detector: 150°C.

Vaporizer: 150°C.

Carrier gas volume: nitrogen: 35 mL/min.

Hydrogen: 35 mL/min.

Air: 350 mL/min.

The pre-column pressure is about 108 kPa.
Application: GB 15979-2002 Hygiene Standard for Disposable Hygiene Products

Haohan Chromatography (Shandong) Application Technology Development Co., Ltd. has established a method for the determination of trace amounts of ethylene oxide in medical masks by purge and trap-gas chromatography/mass spectrometry. The ethylene oxide in the medical masks was enriched by the purge and trap method, and then introduced into a gas chromatography/mass spectrometer after thermal desorption. The results showed that the linear relationship of ethylene oxide was good in the mass concentration range of 5.0～200μg/L, the correlation coefficient was 0.9992, the detection limit was 0.03μg/g, and the quantification limit was 0.10μg/g. The recoveries of the three spiked levels (5.0μg/L, 20μg/L, 80μg/L) were 97.59%-115.95%, and the relative standard deviations (RSD, n=6) were 3.07%-7.48%. The method is simple to operate, has high enrichment efficiency, is fast and accurate, and is suitable for the determination of large quantities of medical mask samples.

Determination of trace ethylene oxide in medical masks GB 15979-2002 test spectrum: